This course from Microsoft E-Learning, with an introduction from Rick LaPlante, is available through a free, 90–day subscription:
Clinic 2551: Introduction to Visual Studio Team System
This Clinic will provide both Business Decision Makers (BDMs) and Technical Decision Makers (TDMs), Architects, Developers, Testers, and Project Managers with an introduction to Visual Studio Team System. This introduction will explain what the product is, how it relates to the software development lifecycle and how processes such as MSF fit it.
This course will offer:
Detailed information about software concepts and principles, and the skills and knowledge required to complete the tasks necessary for your job role.
Hands-on lab activities to practice new skills in the actual environment you would deploy in your organization.
A progress-tracking feature to indicate the course content you have started or completed.
Offline functionality - download the course and review the content offline, then synchronize your progress the next time you are online.
Terminal and enabling learning objectives.
Multimedia learning components (which may include animations, demonstrations, or simulations with audio and transcripts).
Full-text search and contextual notes.
UPDATE - D'uh. Here's the link to the course: Visual Studio 2005 E-Learning. Thanks, Omar.