You want to start writing a piece of software but you are an absolute beginner, what do you do?
Check out this site on MSDN: http://msdn.microsoft.com/vstudio/express/beginner/
Choose between web development and windows development and get started reading and of course also writing code! An overview of the learning paths can be found here: http://msdn.microsoft.com/vstudio/express/beginner/learningpath/
And you just got to check out the kids corner, for yourself or for your little Einstein Kid.