Bob Tabor over at LearnvVisualStudio.net built out a great introductory video series to get people up to speed using Visual Web Developer Express and ASP.NET 2.0 to build web sites. The content starts at the very basics and gets more advanced. The first 8 videos are done (about 4 hrs of total content per language) and they are produced in both VB and C#. Over the next few weeks we should be rolling out the final videos which will cover building a survey application end-to-end.
If you are new to ASP.NET or Visual Studio or looking for a quick refresher this is a great way to get involved. Be sure to check out www.learnvisualstudio.net to see other great videos on DotNetNuke, C#, VB, and more.
Check out the videos here: http://lab.msdn.microsoft.com/express/learnvwd/